Chemical reactivity of [(μ-RSe) (μ-S) {Fe2(CO)6}24-S)]-: Synthesis and characterization of (μ-RSe) (μ-R'S) {Fe2(CO)6}24-S) and (μ3-S)2Fe3 (CO)8 [Se(Ph)Fe(CO)2Cp]

Huai Ben Zheng, Shaobin Miao, Zhong Xia Wang, Zhong Yuan Zhou, Xiang Ge Zhou

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

The reaction Of (μ-S2)Fe2(CO)6 with [(μ-RSe) (μ-CO)Fe2(CO)6]- gives the anionic complexes [(μ-RSe) (μ-S){Fe2(CO)6}24-S)]- (1). Reactions of 1 with electrophiles such as alkyl halides, acid chlorides and PhN2BF4 form neutral complexes (μ-RSe)(μ-R'S) [Fe2(CO)6]24-S) (R = Ph, R' = Me 2a; R = Ph, R' = PhCH2 2b; R = Et, R' = Me 2c; R = Ph, R' = CH3C(O) 3a; R = Ph, R' = PhC(O) 3b; R = Et, R' = PhC(O) 3c; R = R' = Ph 4). Treatment of 1 with Cp(CO)2FeI affords pentanuclear iron complexes (μ-RSe)[μ-Cp(CO)2FeS][Fe2(CO)6]24-S) (R = Ph 5a; R = Et 5b). From the reaction mixture of 1 (R = Ph) and Cp(CO)2FeI, (μ3-S)2Fe3(CO)8[Se(Ph)Fe(CO)2Cp] (6) was also obtained. The structure of complex 6 was determined by single-crystal X-ray analysis. (C) 2000 Elsevier Science Ltd.

Original languageEnglish (US)
Pages (from-to)713-718
Number of pages6
JournalPolyhedron
Volume19
Issue number6
DOIs
StatePublished - Mar 30 2000

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Chemical reactivity
X ray analysis
Carbon Monoxide
reactivity
Single crystals
Iron
Acids
synthesis
halides
chlorides
iron
Chlorides
acids
single crystals

Keywords

  • Iron
  • Reaction
  • Selenium
  • Sulfur
  • Synthesis

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Chemical reactivity of [(μ-RSe) (μ-S) {Fe2(CO)6}24-S)]- : Synthesis and characterization of (μ-RSe) (μ-R'S) {Fe2(CO)6}24-S) and (μ3-S)2Fe3 (CO)8 [Se(Ph)Fe(CO)2Cp]. / Zheng, Huai Ben; Miao, Shaobin; Wang, Zhong Xia; Zhou, Zhong Yuan; Zhou, Xiang Ge.

In: Polyhedron, Vol. 19, No. 6, 30.03.2000, p. 713-718.

Research output: Contribution to journalArticle

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title = "Chemical reactivity of [(μ-RSe) (μ-S) {Fe2(CO)6}2(μ4-S)]-: Synthesis and characterization of (μ-RSe) (μ-R'S) {Fe2(CO)6}2(μ4-S) and (μ3-S)2Fe3 (CO)8 [Se(Ph)Fe(CO)2Cp]",
abstract = "The reaction Of (μ-S2)Fe2(CO)6 with [(μ-RSe) (μ-CO)Fe2(CO)6]- gives the anionic complexes [(μ-RSe) (μ-S){Fe2(CO)6}2(μ4-S)]- (1). Reactions of 1 with electrophiles such as alkyl halides, acid chlorides and PhN2BF4 form neutral complexes (μ-RSe)(μ-R'S) [Fe2(CO)6]2(μ4-S) (R = Ph, R' = Me 2a; R = Ph, R' = PhCH2 2b; R = Et, R' = Me 2c; R = Ph, R' = CH3C(O) 3a; R = Ph, R' = PhC(O) 3b; R = Et, R' = PhC(O) 3c; R = R' = Ph 4). Treatment of 1 with Cp(CO)2FeI affords pentanuclear iron complexes (μ-RSe)[μ-Cp(CO)2FeS][Fe2(CO)6]2(μ4-S) (R = Ph 5a; R = Et 5b). From the reaction mixture of 1 (R = Ph) and Cp(CO)2FeI, (μ3-S)2Fe3(CO)8[Se(Ph)Fe(CO)2Cp] (6) was also obtained. The structure of complex 6 was determined by single-crystal X-ray analysis. (C) 2000 Elsevier Science Ltd.",
keywords = "Iron, Reaction, Selenium, Sulfur, Synthesis",
author = "Zheng, {Huai Ben} and Shaobin Miao and Wang, {Zhong Xia} and Zhou, {Zhong Yuan} and Zhou, {Xiang Ge}",
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T1 - Chemical reactivity of [(μ-RSe) (μ-S) {Fe2(CO)6}2(μ4-S)]-

T2 - Synthesis and characterization of (μ-RSe) (μ-R'S) {Fe2(CO)6}2(μ4-S) and (μ3-S)2Fe3 (CO)8 [Se(Ph)Fe(CO)2Cp]

AU - Zheng, Huai Ben

AU - Miao, Shaobin

AU - Wang, Zhong Xia

AU - Zhou, Zhong Yuan

AU - Zhou, Xiang Ge

PY - 2000/3/30

Y1 - 2000/3/30

N2 - The reaction Of (μ-S2)Fe2(CO)6 with [(μ-RSe) (μ-CO)Fe2(CO)6]- gives the anionic complexes [(μ-RSe) (μ-S){Fe2(CO)6}2(μ4-S)]- (1). Reactions of 1 with electrophiles such as alkyl halides, acid chlorides and PhN2BF4 form neutral complexes (μ-RSe)(μ-R'S) [Fe2(CO)6]2(μ4-S) (R = Ph, R' = Me 2a; R = Ph, R' = PhCH2 2b; R = Et, R' = Me 2c; R = Ph, R' = CH3C(O) 3a; R = Ph, R' = PhC(O) 3b; R = Et, R' = PhC(O) 3c; R = R' = Ph 4). Treatment of 1 with Cp(CO)2FeI affords pentanuclear iron complexes (μ-RSe)[μ-Cp(CO)2FeS][Fe2(CO)6]2(μ4-S) (R = Ph 5a; R = Et 5b). From the reaction mixture of 1 (R = Ph) and Cp(CO)2FeI, (μ3-S)2Fe3(CO)8[Se(Ph)Fe(CO)2Cp] (6) was also obtained. The structure of complex 6 was determined by single-crystal X-ray analysis. (C) 2000 Elsevier Science Ltd.

AB - The reaction Of (μ-S2)Fe2(CO)6 with [(μ-RSe) (μ-CO)Fe2(CO)6]- gives the anionic complexes [(μ-RSe) (μ-S){Fe2(CO)6}2(μ4-S)]- (1). Reactions of 1 with electrophiles such as alkyl halides, acid chlorides and PhN2BF4 form neutral complexes (μ-RSe)(μ-R'S) [Fe2(CO)6]2(μ4-S) (R = Ph, R' = Me 2a; R = Ph, R' = PhCH2 2b; R = Et, R' = Me 2c; R = Ph, R' = CH3C(O) 3a; R = Ph, R' = PhC(O) 3b; R = Et, R' = PhC(O) 3c; R = R' = Ph 4). Treatment of 1 with Cp(CO)2FeI affords pentanuclear iron complexes (μ-RSe)[μ-Cp(CO)2FeS][Fe2(CO)6]2(μ4-S) (R = Ph 5a; R = Et 5b). From the reaction mixture of 1 (R = Ph) and Cp(CO)2FeI, (μ3-S)2Fe3(CO)8[Se(Ph)Fe(CO)2Cp] (6) was also obtained. The structure of complex 6 was determined by single-crystal X-ray analysis. (C) 2000 Elsevier Science Ltd.

KW - Iron

KW - Reaction

KW - Selenium

KW - Sulfur

KW - Synthesis

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JO - Polyhedron

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