Derivatives of octaethynylphenazine and hexaethynylquinoxaline

Shaobin Miao, Carlito G. Bangcuyo, Mark D. Smith, Uwe H.F. Bunz

Research output: Contribution to journalArticle

21 Scopus citations

Abstract

Pocketing metals with alkynes: The spectral responses of the peralkynylated heteroacenes hexaethynylquinoxaline and octaethynylphenazine (see structure; N blue, C red, H yellow) on the presence of metal cations are more-pronounced for the phenazine derivative, demonstrating that the presence of the lateral alkyne substituents improves the metal-ion-binding capability of the pyrazine motif. (Figure Presented)

Original languageEnglish (US)
Pages (from-to)661-665
Number of pages5
JournalAngewandte Chemie - International Edition
Volume45
Issue number4
DOIs
Publication statusPublished - Jan 16 2006
Externally publishedYes

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Keywords

  • Alkynes
  • Cations
  • Fused-ring systems
  • Nitrogen heterocycles

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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