Disulfido iron-manganese carbonyl cluster complexes: Synthesis, structure, bonding and properties of the radical CpFeMn2(CO)73-S2)2

Richard D. Adams, Erin M. Boswell, Burjor Captain, Shaobin Miao, Chad Beddie, Charles Edwin Webster, Michael B. Hall, Naresh S. Dalal, Narpinder Kaur, David Zipse

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

Two new compounds CpFeMn2(CO)73-S2)2 (2) and Cp3Fe3Mn(CO)43-S 2)23-S) (3) were obtained by the treatment of [CpFeMn(CO)53-S2)]2 (1) with CO at room temperature in the presence of room light.

Original languageEnglish (US)
Pages (from-to)2732-2738
Number of pages7
JournalJournal of Organometallic Chemistry
Volume693
Issue number16
DOIs
StatePublished - Aug 1 2008

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Manganese
rooms
manganese
Iron
Light
iron
Temperature
room temperature
synthesis

Keywords

  • Disulfido
  • Iron
  • Manganese
  • Molecular orbitals
  • Radical

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Disulfido iron-manganese carbonyl cluster complexes : Synthesis, structure, bonding and properties of the radical CpFeMn2(CO)73-S2)2 . / Adams, Richard D.; Boswell, Erin M.; Captain, Burjor; Miao, Shaobin; Beddie, Chad; Webster, Charles Edwin; Hall, Michael B.; Dalal, Naresh S.; Kaur, Narpinder; Zipse, David.

In: Journal of Organometallic Chemistry, Vol. 693, No. 16, 01.08.2008, p. 2732-2738.

Research output: Contribution to journalArticle

Adams, Richard D. ; Boswell, Erin M. ; Captain, Burjor ; Miao, Shaobin ; Beddie, Chad ; Webster, Charles Edwin ; Hall, Michael B. ; Dalal, Naresh S. ; Kaur, Narpinder ; Zipse, David. / Disulfido iron-manganese carbonyl cluster complexes : Synthesis, structure, bonding and properties of the radical CpFeMn2(CO)73-S2)2 . In: Journal of Organometallic Chemistry. 2008 ; Vol. 693, No. 16. pp. 2732-2738.
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abstract = "Two new compounds CpFeMn2(CO)7(μ3-S2)2 (2) and Cp3Fe3Mn(CO)4(μ3-S 2)2(μ3-S) (3) were obtained by the treatment of [CpFeMn(CO)5(μ3-S2)]2 (1) with CO at room temperature in the presence of room light.",
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AU - Beddie, Chad

AU - Webster, Charles Edwin

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AB - Two new compounds CpFeMn2(CO)7(μ3-S2)2 (2) and Cp3Fe3Mn(CO)4(μ3-S 2)2(μ3-S) (3) were obtained by the treatment of [CpFeMn(CO)5(μ3-S2)]2 (1) with CO at room temperature in the presence of room light.

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KW - Manganese

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