Double-resonance spectroscopy of the high Rydberg states of HCO. V. Rovibronic interactions and l-uncoupling in the (010) manifold

Eric J Zuckerman, Eric E. Mayer, Robert J. Foltynowicz, Jason D. Robinson, Shi Hui Jen, Michael C. Konopka, Todd Sanford, Hartmut G. Hedderich, I. Chia Chen, Edward R. Grant

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

Ionization-detected absorption spectra of autoionization Rydberg states converging to the (010) vibrational level of HCO PLU was reported. Sharp second-photon resonances were observed in transitions from first-photon-prepared transition states. The spectra was compared in order to characterize observed resonances in terms of good angular momentum quantum number, N. The convergence of series to detailed cation-ore rotational quantum numbers, N + was established by Rydberg analysis.

Original languageEnglish (US)
Pages (from-to)5372-5383
Number of pages12
JournalJournal of Chemical Physics
Volume113
Issue number13
DOIs
StatePublished - Oct 1 2000

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Rydberg states
quantum numbers
Photons
Spectroscopy
Angular momentum
autoionization
photons
spectroscopy
Ores
Ionization
Cations
Absorption spectra
angular momentum
minerals
interactions
absorption spectra
cations
ionization

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Cite this

Zuckerman, E. J., Mayer, E. E., Foltynowicz, R. J., Robinson, J. D., Jen, S. H., Konopka, M. C., ... Grant, E. R. (2000). Double-resonance spectroscopy of the high Rydberg states of HCO. V. Rovibronic interactions and l-uncoupling in the (010) manifold. Journal of Chemical Physics, 113(13), 5372-5383. https://doi.org/10.1063/1.1290032

Double-resonance spectroscopy of the high Rydberg states of HCO. V. Rovibronic interactions and l-uncoupling in the (010) manifold. / Zuckerman, Eric J; Mayer, Eric E.; Foltynowicz, Robert J.; Robinson, Jason D.; Jen, Shi Hui; Konopka, Michael C.; Sanford, Todd; Hedderich, Hartmut G.; Chen, I. Chia; Grant, Edward R.

In: Journal of Chemical Physics, Vol. 113, No. 13, 01.10.2000, p. 5372-5383.

Research output: Contribution to journalArticle

Zuckerman, EJ, Mayer, EE, Foltynowicz, RJ, Robinson, JD, Jen, SH, Konopka, MC, Sanford, T, Hedderich, HG, Chen, IC & Grant, ER 2000, 'Double-resonance spectroscopy of the high Rydberg states of HCO. V. Rovibronic interactions and l-uncoupling in the (010) manifold', Journal of Chemical Physics, vol. 113, no. 13, pp. 5372-5383. https://doi.org/10.1063/1.1290032
Zuckerman, Eric J ; Mayer, Eric E. ; Foltynowicz, Robert J. ; Robinson, Jason D. ; Jen, Shi Hui ; Konopka, Michael C. ; Sanford, Todd ; Hedderich, Hartmut G. ; Chen, I. Chia ; Grant, Edward R. / Double-resonance spectroscopy of the high Rydberg states of HCO. V. Rovibronic interactions and l-uncoupling in the (010) manifold. In: Journal of Chemical Physics. 2000 ; Vol. 113, No. 13. pp. 5372-5383.
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