Double-resonance spectroscopy of the high Rydberg states of HCO. V. Rovibronic interactions and l-uncoupling in the (010) manifold

Eric J Zuckerman; Eric E. Mayer; Robert J. Foltynowicz; Jason D. Robinson; Shi Hui Jen; Michael C. Konopka; Todd Sanford; Hartmut G. Hedderich; I. Chia Chen; Edward R. Grant

doi:10.1063/1.1290032

Double-resonance spectroscopy of the high Rydberg states of HCO. V. Rovibronic interactions and l-uncoupling in the (010) manifold

Eric J Zuckerman, Eric E. Mayer, Robert J. Foltynowicz, Jason D. Robinson, Shi Hui Jen, Michael C. Konopka, Todd Sanford, Hartmut G. Hedderich, I. Chia Chen, Edward R. Grant

Chemistry and Physics

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Ionization-detected absorption spectra of autoionization Rydberg states converging to the (010) vibrational level of HCO^PLU was reported. Sharp second-photon resonances were observed in transitions from first-photon-prepared transition states. The spectra was compared in order to characterize observed resonances in terms of good angular momentum quantum number, N. The convergence of series to detailed cation-ore rotational quantum numbers, N⁺ was established by Rydberg analysis.

Original language	English (US)
Pages (from-to)	5372-5383
Number of pages	12
Journal	Journal of Chemical Physics
Volume	113
Issue number	13
DOIs	https://doi.org/10.1063/1.1290032
State	Published - Oct 1 2000

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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10.1063/1.1290032

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Zuckerman, E. J., Mayer, E. E., Foltynowicz, R. J., Robinson, J. D., Jen, S. H., Konopka, M. C., Sanford, T., Hedderich, H. G., Chen, I. C., & Grant, E. R. (2000). Double-resonance spectroscopy of the high Rydberg states of HCO. V. Rovibronic interactions and l-uncoupling in the (010) manifold. Journal of Chemical Physics, 113(13), 5372-5383. https://doi.org/10.1063/1.1290032

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abstract = "Ionization-detected absorption spectra of autoionization Rydberg states converging to the (010) vibrational level of HCOPLU was reported. Sharp second-photon resonances were observed in transitions from first-photon-prepared transition states. The spectra was compared in order to characterize observed resonances in terms of good angular momentum quantum number, N. The convergence of series to detailed cation-ore rotational quantum numbers, N+ was established by Rydberg analysis.",

author = "Zuckerman, {Eric J} and Mayer, {Eric E.} and Foltynowicz, {Robert J.} and Robinson, {Jason D.} and Jen, {Shi Hui} and Konopka, {Michael C.} and Todd Sanford and Hedderich, {Hartmut G.} and Chen, {I. Chia} and Grant, {Edward R.}",

year = "2000",

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doi = "10.1063/1.1290032",

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T1 - Double-resonance spectroscopy of the high Rydberg states of HCO. V. Rovibronic interactions and l-uncoupling in the (010) manifold

AU - Zuckerman, Eric J

AU - Mayer, Eric E.

AU - Foltynowicz, Robert J.

AU - Robinson, Jason D.

AU - Jen, Shi Hui

AU - Konopka, Michael C.

AU - Sanford, Todd

AU - Hedderich, Hartmut G.

AU - Chen, I. Chia

AU - Grant, Edward R.

PY - 2000/10/1

Y1 - 2000/10/1

N2 - Ionization-detected absorption spectra of autoionization Rydberg states converging to the (010) vibrational level of HCOPLU was reported. Sharp second-photon resonances were observed in transitions from first-photon-prepared transition states. The spectra was compared in order to characterize observed resonances in terms of good angular momentum quantum number, N. The convergence of series to detailed cation-ore rotational quantum numbers, N+ was established by Rydberg analysis.

AB - Ionization-detected absorption spectra of autoionization Rydberg states converging to the (010) vibrational level of HCOPLU was reported. Sharp second-photon resonances were observed in transitions from first-photon-prepared transition states. The spectra was compared in order to characterize observed resonances in terms of good angular momentum quantum number, N. The convergence of series to detailed cation-ore rotational quantum numbers, N+ was established by Rydberg analysis.

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ER -

Double-resonance spectroscopy of the high Rydberg states of HCO. V. Rovibronic interactions and l-uncoupling in the (010) manifold

Abstract

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