Double-resonance spectroscopy of the high Rydberg states of HCO. V. Rovibronic interactions and l-uncoupling in the (010) manifold

Eric J Zuckerman, Eric E. Mayer, Robert J. Foltynowicz, Jason D. Robinson, Shi Hui Jen, Michael C. Konopka, Todd Sanford, Hartmut G. Hedderich, I. Chia Chen, Edward R. Grant

Research output: Contribution to journalArticle

9 Scopus citations

Abstract

Ionization-detected absorption spectra of autoionization Rydberg states converging to the (010) vibrational level of HCOPLU was reported. Sharp second-photon resonances were observed in transitions from first-photon-prepared transition states. The spectra was compared in order to characterize observed resonances in terms of good angular momentum quantum number, N. The convergence of series to detailed cation-ore rotational quantum numbers, N+ was established by Rydberg analysis.

Original languageEnglish (US)
Pages (from-to)5372-5383
Number of pages12
JournalJournal of Chemical Physics
Volume113
Issue number13
DOIs
StatePublished - Oct 1 2000

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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    Zuckerman, E. J., Mayer, E. E., Foltynowicz, R. J., Robinson, J. D., Jen, S. H., Konopka, M. C., Sanford, T., Hedderich, H. G., Chen, I. C., & Grant, E. R. (2000). Double-resonance spectroscopy of the high Rydberg states of HCO. V. Rovibronic interactions and l-uncoupling in the (010) manifold. Journal of Chemical Physics, 113(13), 5372-5383. https://doi.org/10.1063/1.1290032