Heptacarbonyl(Disulfido)Dimanganese(I)

Richard D. Adams; O. Sung Kwon; Shaobin Miao; Cameron W. Spahn; Thomas B. Rauchfuss

doi:10.1002/9781118744994.ch22

Heptacarbonyl(Disulfido)Dimanganese(I)

Richard D. Adams, O. Sung Kwon, Shaobin Miao, Cameron W. Spahn, Thomas B. Rauchfuss

Research output: Chapter in Book/Report/Conference proceeding › Chapter

Abstract

This chapter describes a convenient procedure for the preparation of heptacarbonyldisulfidodimanganese, Mn2(CO)7(μ-S2), from the acetonitrile derivative of Mn2(CO)10 and the strained cyclic thioether known as thiirane (SCH2CH2), which serves as a source of sulfur. Thiirane (ethylene sulfide) can be purchased from Aldrich Chemical Company and should be vacuum distilled before use. The Mn2(CO)9(NCMe) is readily prepared by treatment of Mn2(CO)10 with trimethylamine N-oxide in acetonitrile. The chapter discusses the procedures and properties of heptacarbonyldisulfidodimanganese.

Original language	English (US)
Title of host publication	Inorganic Syntheses
Publisher	Wiley-Blackwell
Pages	123-125
Number of pages	3
Volume	36
ISBN (Electronic)	9781118744994
ISBN (Print)	9781118744871
DOIs	https://doi.org/10.1002/9781118744994.ch22
State	Published - May 12 2014
Externally published	Yes

Keywords

Aldrich Chemical Company
Heptacarbonyldisulfidodimanganese

ASJC Scopus subject areas

General Chemistry
General Engineering
General Materials Science

Access to Document

10.1002/9781118744994.ch22

Cite this

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abstract = "This chapter describes a convenient procedure for the preparation of heptacarbonyldisulfidodimanganese, Mn2(CO)7(μ-S2), from the acetonitrile derivative of Mn2(CO)10 and the strained cyclic thioether known as thiirane (SCH2CH2), which serves as a source of sulfur. Thiirane (ethylene sulfide) can be purchased from Aldrich Chemical Company and should be vacuum distilled before use. The Mn2(CO)9(NCMe) is readily prepared by treatment of Mn2(CO)10 with trimethylamine N-oxide in acetonitrile. The chapter discusses the procedures and properties of heptacarbonyldisulfidodimanganese.",

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AU - Adams, Richard D.

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AU - Miao, Shaobin

AU - Spahn, Cameron W.

AU - Rauchfuss, Thomas B.

PY - 2014/5/12

Y1 - 2014/5/12

N2 - This chapter describes a convenient procedure for the preparation of heptacarbonyldisulfidodimanganese, Mn2(CO)7(μ-S2), from the acetonitrile derivative of Mn2(CO)10 and the strained cyclic thioether known as thiirane (SCH2CH2), which serves as a source of sulfur. Thiirane (ethylene sulfide) can be purchased from Aldrich Chemical Company and should be vacuum distilled before use. The Mn2(CO)9(NCMe) is readily prepared by treatment of Mn2(CO)10 with trimethylamine N-oxide in acetonitrile. The chapter discusses the procedures and properties of heptacarbonyldisulfidodimanganese.

AB - This chapter describes a convenient procedure for the preparation of heptacarbonyldisulfidodimanganese, Mn2(CO)7(μ-S2), from the acetonitrile derivative of Mn2(CO)10 and the strained cyclic thioether known as thiirane (SCH2CH2), which serves as a source of sulfur. Thiirane (ethylene sulfide) can be purchased from Aldrich Chemical Company and should be vacuum distilled before use. The Mn2(CO)9(NCMe) is readily prepared by treatment of Mn2(CO)10 with trimethylamine N-oxide in acetonitrile. The chapter discusses the procedures and properties of heptacarbonyldisulfidodimanganese.

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KW - Heptacarbonyldisulfidodimanganese

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Heptacarbonyl(Disulfido)Dimanganese(I)

Abstract

Keywords

ASJC Scopus subject areas

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