Heptacarbonyl(Disulfido)Dimanganese(I)

Richard D. Adams, O. Sung Kwon, Shaobin Miao, Cameron W. Spahn, Thomas B. Rauchfuss

Research output: Chapter in Book/Report/Conference proceedingChapter

Abstract

This chapter describes a convenient procedure for the preparation of heptacarbonyldisulfidodimanganese, Mn2(CO)7(μ-S2), from the acetonitrile derivative of Mn2(CO)10 and the strained cyclic thioether known as thiirane (SCH2CH2), which serves as a source of sulfur. Thiirane (ethylene sulfide) can be purchased from Aldrich Chemical Company and should be vacuum distilled before use. The Mn2(CO)9(NCMe) is readily prepared by treatment of Mn2(CO)10 with trimethylamine N-oxide in acetonitrile. The chapter discusses the procedures and properties of heptacarbonyldisulfidodimanganese.

Original languageEnglish (US)
Title of host publicationInorganic Syntheses
PublisherWiley-Blackwell
Pages123-125
Number of pages3
Volume36
ISBN (Electronic)9781118744994
ISBN (Print)9781118744871
DOIs
StatePublished - May 12 2014

Fingerprint

Acetonitrile
Carbon Monoxide
Ethylene
Sulfur
Vacuum
Sulfides
Derivatives
Oxides
Industry
ethylene sulfide
dimanganese decacarbonyl
acetonitrile

Keywords

  • Aldrich Chemical Company
  • Heptacarbonyldisulfidodimanganese

ASJC Scopus subject areas

  • Chemistry(all)
  • Engineering(all)
  • Materials Science(all)

Cite this

Adams, R. D., Kwon, O. S., Miao, S., Spahn, C. W., & Rauchfuss, T. B. (2014). Heptacarbonyl(Disulfido)Dimanganese(I). In Inorganic Syntheses (Vol. 36, pp. 123-125). Wiley-Blackwell. https://doi.org/10.1002/9781118744994.ch22

Heptacarbonyl(Disulfido)Dimanganese(I). / Adams, Richard D.; Kwon, O. Sung; Miao, Shaobin; Spahn, Cameron W.; Rauchfuss, Thomas B.

Inorganic Syntheses. Vol. 36 Wiley-Blackwell, 2014. p. 123-125.

Research output: Chapter in Book/Report/Conference proceedingChapter

Adams, RD, Kwon, OS, Miao, S, Spahn, CW & Rauchfuss, TB 2014, Heptacarbonyl(Disulfido)Dimanganese(I). in Inorganic Syntheses. vol. 36, Wiley-Blackwell, pp. 123-125. https://doi.org/10.1002/9781118744994.ch22
Adams RD, Kwon OS, Miao S, Spahn CW, Rauchfuss TB. Heptacarbonyl(Disulfido)Dimanganese(I). In Inorganic Syntheses. Vol. 36. Wiley-Blackwell. 2014. p. 123-125 https://doi.org/10.1002/9781118744994.ch22
Adams, Richard D. ; Kwon, O. Sung ; Miao, Shaobin ; Spahn, Cameron W. ; Rauchfuss, Thomas B. / Heptacarbonyl(Disulfido)Dimanganese(I). Inorganic Syntheses. Vol. 36 Wiley-Blackwell, 2014. pp. 123-125
@inbook{95d1b9085e484d6ba1708a113ab3a8b2,
title = "Heptacarbonyl(Disulfido)Dimanganese(I)",
abstract = "This chapter describes a convenient procedure for the preparation of heptacarbonyldisulfidodimanganese, Mn2(CO)7(μ-S2), from the acetonitrile derivative of Mn2(CO)10 and the strained cyclic thioether known as thiirane (SCH2CH2), which serves as a source of sulfur. Thiirane (ethylene sulfide) can be purchased from Aldrich Chemical Company and should be vacuum distilled before use. The Mn2(CO)9(NCMe) is readily prepared by treatment of Mn2(CO)10 with trimethylamine N-oxide in acetonitrile. The chapter discusses the procedures and properties of heptacarbonyldisulfidodimanganese.",
keywords = "Aldrich Chemical Company, Heptacarbonyldisulfidodimanganese",
author = "Adams, {Richard D.} and Kwon, {O. Sung} and Shaobin Miao and Spahn, {Cameron W.} and Rauchfuss, {Thomas B.}",
year = "2014",
month = "5",
day = "12",
doi = "10.1002/9781118744994.ch22",
language = "English (US)",
isbn = "9781118744871",
volume = "36",
pages = "123--125",
booktitle = "Inorganic Syntheses",
publisher = "Wiley-Blackwell",
address = "United States",

}

TY - CHAP

T1 - Heptacarbonyl(Disulfido)Dimanganese(I)

AU - Adams, Richard D.

AU - Kwon, O. Sung

AU - Miao, Shaobin

AU - Spahn, Cameron W.

AU - Rauchfuss, Thomas B.

PY - 2014/5/12

Y1 - 2014/5/12

N2 - This chapter describes a convenient procedure for the preparation of heptacarbonyldisulfidodimanganese, Mn2(CO)7(μ-S2), from the acetonitrile derivative of Mn2(CO)10 and the strained cyclic thioether known as thiirane (SCH2CH2), which serves as a source of sulfur. Thiirane (ethylene sulfide) can be purchased from Aldrich Chemical Company and should be vacuum distilled before use. The Mn2(CO)9(NCMe) is readily prepared by treatment of Mn2(CO)10 with trimethylamine N-oxide in acetonitrile. The chapter discusses the procedures and properties of heptacarbonyldisulfidodimanganese.

AB - This chapter describes a convenient procedure for the preparation of heptacarbonyldisulfidodimanganese, Mn2(CO)7(μ-S2), from the acetonitrile derivative of Mn2(CO)10 and the strained cyclic thioether known as thiirane (SCH2CH2), which serves as a source of sulfur. Thiirane (ethylene sulfide) can be purchased from Aldrich Chemical Company and should be vacuum distilled before use. The Mn2(CO)9(NCMe) is readily prepared by treatment of Mn2(CO)10 with trimethylamine N-oxide in acetonitrile. The chapter discusses the procedures and properties of heptacarbonyldisulfidodimanganese.

KW - Aldrich Chemical Company

KW - Heptacarbonyldisulfidodimanganese

UR - http://www.scopus.com/inward/record.url?scp=84927681208&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84927681208&partnerID=8YFLogxK

U2 - 10.1002/9781118744994.ch22

DO - 10.1002/9781118744994.ch22

M3 - Chapter

AN - SCOPUS:84927681208

SN - 9781118744871

VL - 36

SP - 123

EP - 125

BT - Inorganic Syntheses

PB - Wiley-Blackwell

ER -