Light-promoted addition of alkenes, dienes, C 60, and disulfur to the disulfido ligand in the complex CpMoMn(CO) 5(μ-S 2)

Richard D. Adams; Shaobin Miao; Mark D. Smith

doi:10.1021/om049811s

Light-promoted addition of alkenes, dienes, C ₆₀, and disulfur to the disulfido ligand in the complex CpMoMn(CO) ₅(μ-S ₂)

Richard D. Adams, Shaobin Miao, Mark D. Smith

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

The alkenes, cis-butene, C ₁₂H ₈ (acenaphthylene), and dienes, 1,3-butadiene and cyclopentadiene, were found to add to the mixed-metal disulfido complex CpMoMn(CO) ₅(μ-S ₂), 1, in the presence of irradiation by visible light to yield the new compounds CpMoMn(CO) ₅[μS ₂CH(CH ₃)CH(CH ₃)], 2, CpMoMn(CO) ₅(μ-S ₂H ₃), 3, CpMoMn(CO) ₅[μ-S ₂CH ₂CH(CH=CH ₂)], 4, and CpMoMn(CO) ₅(μ-S ₂C ₅H ₆), 5, by 1,2-insertion of a C-C double bond into the S-S bond of 1. The cis-butene was inserted into the S-S bond with retention of stereochemistry. The reaction of 1 with C ₆₀ yielded the complex CpMoMn(CO) ₅(μ-S ₂C ₆₀), 6, in the presence of room light. A crystallographic study of 6 showed that the C ₆₀ was inserted into the S-S bond at one of its 6,6 ring junctions. The reaction of 1 with elemental sulfur yielded the tetrasulfido complex CpMoMn(CO) ₅(μ-S ₄), 7, by addition of an S ₂ group to the disulfido ligand. All new complexes were characterized by single-crystal X-ray diffraction analysis.

Original language	English (US)
Pages (from-to)	3327-3334
Number of pages	8
Journal	Organometallics
Volume	23
Issue number	13
DOIs	https://doi.org/10.1021/om049811s
State	Published - Jun 21 2004
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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@article{5cee200b17a440c9bebcb5677e9c00e1,

title = "Light-promoted addition of alkenes, dienes, C 60, and disulfur to the disulfido ligand in the complex CpMoMn(CO) 5(μ-S 2)",

abstract = "The alkenes, cis-butene, C 12H 8 (acenaphthylene), and dienes, 1,3-butadiene and cyclopentadiene, were found to add to the mixed-metal disulfido complex CpMoMn(CO) 5(μ-S 2), 1, in the presence of irradiation by visible light to yield the new compounds CpMoMn(CO) 5[μS 2CH(CH 3)CH(CH 3)], 2, CpMoMn(CO) 5(μ-S 2H 3), 3, CpMoMn(CO) 5[μ-S 2CH 2CH(CH=CH 2)], 4, and CpMoMn(CO) 5(μ-S 2C 5H 6), 5, by 1,2-insertion of a C-C double bond into the S-S bond of 1. The cis-butene was inserted into the S-S bond with retention of stereochemistry. The reaction of 1 with C 60 yielded the complex CpMoMn(CO) 5(μ-S 2C 60), 6, in the presence of room light. A crystallographic study of 6 showed that the C 60 was inserted into the S-S bond at one of its 6,6 ring junctions. The reaction of 1 with elemental sulfur yielded the tetrasulfido complex CpMoMn(CO) 5(μ-S 4), 7, by addition of an S 2 group to the disulfido ligand. All new complexes were characterized by single-crystal X-ray diffraction analysis.",

author = "Adams, {Richard D.} and Shaobin Miao and Smith, {Mark D.}",

year = "2004",

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doi = "10.1021/om049811s",

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T1 - Light-promoted addition of alkenes, dienes, C 60, and disulfur to the disulfido ligand in the complex CpMoMn(CO) 5(μ-S 2)

AU - Adams, Richard D.

AU - Miao, Shaobin

AU - Smith, Mark D.

PY - 2004/6/21

Y1 - 2004/6/21

N2 - The alkenes, cis-butene, C 12H 8 (acenaphthylene), and dienes, 1,3-butadiene and cyclopentadiene, were found to add to the mixed-metal disulfido complex CpMoMn(CO) 5(μ-S 2), 1, in the presence of irradiation by visible light to yield the new compounds CpMoMn(CO) 5[μS 2CH(CH 3)CH(CH 3)], 2, CpMoMn(CO) 5(μ-S 2H 3), 3, CpMoMn(CO) 5[μ-S 2CH 2CH(CH=CH 2)], 4, and CpMoMn(CO) 5(μ-S 2C 5H 6), 5, by 1,2-insertion of a C-C double bond into the S-S bond of 1. The cis-butene was inserted into the S-S bond with retention of stereochemistry. The reaction of 1 with C 60 yielded the complex CpMoMn(CO) 5(μ-S 2C 60), 6, in the presence of room light. A crystallographic study of 6 showed that the C 60 was inserted into the S-S bond at one of its 6,6 ring junctions. The reaction of 1 with elemental sulfur yielded the tetrasulfido complex CpMoMn(CO) 5(μ-S 4), 7, by addition of an S 2 group to the disulfido ligand. All new complexes were characterized by single-crystal X-ray diffraction analysis.

AB - The alkenes, cis-butene, C 12H 8 (acenaphthylene), and dienes, 1,3-butadiene and cyclopentadiene, were found to add to the mixed-metal disulfido complex CpMoMn(CO) 5(μ-S 2), 1, in the presence of irradiation by visible light to yield the new compounds CpMoMn(CO) 5[μS 2CH(CH 3)CH(CH 3)], 2, CpMoMn(CO) 5(μ-S 2H 3), 3, CpMoMn(CO) 5[μ-S 2CH 2CH(CH=CH 2)], 4, and CpMoMn(CO) 5(μ-S 2C 5H 6), 5, by 1,2-insertion of a C-C double bond into the S-S bond of 1. The cis-butene was inserted into the S-S bond with retention of stereochemistry. The reaction of 1 with C 60 yielded the complex CpMoMn(CO) 5(μ-S 2C 60), 6, in the presence of room light. A crystallographic study of 6 showed that the C 60 was inserted into the S-S bond at one of its 6,6 ring junctions. The reaction of 1 with elemental sulfur yielded the tetrasulfido complex CpMoMn(CO) 5(μ-S 4), 7, by addition of an S 2 group to the disulfido ligand. All new complexes were characterized by single-crystal X-ray diffraction analysis.

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Light-promoted addition of alkenes, dienes, C ₆₀, and disulfur to the disulfido ligand in the complex CpMoMn(CO) ₅(μ-S ₂)

Abstract

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