Magnetization transfer via isotropic mixing

An introduction to the HOHAHA experiment

Rickey Paige Hicks, John K. Young, Detlef Moskau

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

The theory of the cross‐polarization two‐dimensional homonuclear Hartmann‐Hahn experiment is introduced. The product operator formalism is used to develop expressions to explain the transfer of magnetization under the influence of the isotropic Hamiltonian. The various modifications of the HOHAHA/TOCSY experiment are presented. The MLEV‐17 pulse cycle for generation of the spin‐lock pulse is discussed in detail. The intensity of magnetization transfer is shown both mathematically and graphically to be dependent on the relationship mixing time 1/(2JAX). The HOHAHA experiment is also discussed in relation to the other spin‐lock experiments, ROESY and CAMELSPIN.

Original languageEnglish (US)
Pages (from-to)115-130
Number of pages16
JournalConcepts in Magnetic Resonance
Volume6
Issue number2
DOIs
StatePublished - Jan 1 1994

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Magnetization
magnetization
pulses
Experiments
formalism
Hamiltonians
operators
cycles
products

ASJC Scopus subject areas

  • Chemistry(all)
  • Spectroscopy
  • Physical and Theoretical Chemistry

Cite this

Magnetization transfer via isotropic mixing : An introduction to the HOHAHA experiment. / Hicks, Rickey Paige; Young, John K.; Moskau, Detlef.

In: Concepts in Magnetic Resonance, Vol. 6, No. 2, 01.01.1994, p. 115-130.

Research output: Contribution to journalArticle

Hicks, Rickey Paige ; Young, John K. ; Moskau, Detlef. / Magnetization transfer via isotropic mixing : An introduction to the HOHAHA experiment. In: Concepts in Magnetic Resonance. 1994 ; Vol. 6, No. 2. pp. 115-130.
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