Metal Carbonyl Derivatives of 1,4-Quinone and 1,4-Hydroquinone

Richard D. Adams, Shaobin Miao

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

CpMoMn(CO)5(μ-S2), 1 reacts with 1,4-benzoquinone to yield CpMoMn(CO)5(μ-S2C6H2O2), 2 containing a 1,4-quinonedithiolato ligand formed by replacing two of the hydrogen atoms on one of the C-C double bonds of 1,4-benzoquinone with sulfur atoms from the disulfido ligand in 1. Compound 2 was reduced with hydrogen to yield CpMoMn(CO)5[μ-S2C6H2(OH)2], 3 which contains a 1,4-hydroquinonedithiolato ligand. Compound 3 was reoxidized to 2 with ferrocenium hexafluorophosphate.

Original languageEnglish (US)
Pages (from-to)5056-5057
Number of pages2
JournalJournal of the American Chemical Society
Volume126
Issue number16
DOIs
StatePublished - Apr 28 2004
Externally publishedYes

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Metals
Ligands
Derivatives
Hydrogen
Atoms
Sulfur
benzoquinone
hydroquinone
ferrocenium

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Metal Carbonyl Derivatives of 1,4-Quinone and 1,4-Hydroquinone. / Adams, Richard D.; Miao, Shaobin.

In: Journal of the American Chemical Society, Vol. 126, No. 16, 28.04.2004, p. 5056-5057.

Research output: Contribution to journalArticle

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AB - CpMoMn(CO)5(μ-S2), 1 reacts with 1,4-benzoquinone to yield CpMoMn(CO)5(μ-S2C6H2O2), 2 containing a 1,4-quinonedithiolato ligand formed by replacing two of the hydrogen atoms on one of the C-C double bonds of 1,4-benzoquinone with sulfur atoms from the disulfido ligand in 1. Compound 2 was reduced with hydrogen to yield CpMoMn(CO)5[μ-S2C6H2(OH)2], 3 which contains a 1,4-hydroquinonedithiolato ligand. Compound 3 was reoxidized to 2 with ferrocenium hexafluorophosphate.

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