Molecular structure and optical nonlinearity of 1,8-bis(ferrocenyl)-3-t- butyl-oct-3-ene-1,5,7-triyne

Shaobin Miao, Qian Feng Zhang, Wa Hung Leung

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Interaction of 1,8-bis(ferrocenyl)-octatetrayne 1 with one equiv. of t-butyl lithium followed by treatment with water gave 1,8-bis(ferrocenyl)-3-t- butyl-oct-3-ene-1,5,7-triyne 2. The solid-state structure of 2, containing a bent carbon chain between two ferrocenes, has been determined. The nonlinear optical properties of 2 were also investigated.

Original languageEnglish (US)
Pages (from-to)714-715
Number of pages2
JournalJournal of Chemical Research
Issue number10
DOIs
StatePublished - Oct 1 2004
Externally publishedYes

Fingerprint

Lithium
Molecular structure
Carbon
Optical properties
Water

Keywords

  • Crystal structures
  • Enynes
  • Ferrocenes
  • Optical nonlinearity
  • Polyynes

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Molecular structure and optical nonlinearity of 1,8-bis(ferrocenyl)-3-t- butyl-oct-3-ene-1,5,7-triyne. / Miao, Shaobin; Zhang, Qian Feng; Leung, Wa Hung.

In: Journal of Chemical Research, No. 10, 01.10.2004, p. 714-715.

Research output: Contribution to journalArticle

@article{2985281c43aa4bcfbd2225aec8071760,
title = "Molecular structure and optical nonlinearity of 1,8-bis(ferrocenyl)-3-t- butyl-oct-3-ene-1,5,7-triyne",
abstract = "Interaction of 1,8-bis(ferrocenyl)-octatetrayne 1 with one equiv. of t-butyl lithium followed by treatment with water gave 1,8-bis(ferrocenyl)-3-t- butyl-oct-3-ene-1,5,7-triyne 2. The solid-state structure of 2, containing a bent carbon chain between two ferrocenes, has been determined. The nonlinear optical properties of 2 were also investigated.",
keywords = "Crystal structures, Enynes, Ferrocenes, Optical nonlinearity, Polyynes",
author = "Shaobin Miao and Zhang, {Qian Feng} and Leung, {Wa Hung}",
year = "2004",
month = "10",
day = "1",
doi = "10.3184/0308234043431771",
language = "English (US)",
pages = "714--715",
journal = "Journal of Chemical Research - Part S",
issn = "0308-2342",
publisher = "Science Reviews Ltd",
number = "10",

}

TY - JOUR

T1 - Molecular structure and optical nonlinearity of 1,8-bis(ferrocenyl)-3-t- butyl-oct-3-ene-1,5,7-triyne

AU - Miao, Shaobin

AU - Zhang, Qian Feng

AU - Leung, Wa Hung

PY - 2004/10/1

Y1 - 2004/10/1

N2 - Interaction of 1,8-bis(ferrocenyl)-octatetrayne 1 with one equiv. of t-butyl lithium followed by treatment with water gave 1,8-bis(ferrocenyl)-3-t- butyl-oct-3-ene-1,5,7-triyne 2. The solid-state structure of 2, containing a bent carbon chain between two ferrocenes, has been determined. The nonlinear optical properties of 2 were also investigated.

AB - Interaction of 1,8-bis(ferrocenyl)-octatetrayne 1 with one equiv. of t-butyl lithium followed by treatment with water gave 1,8-bis(ferrocenyl)-3-t- butyl-oct-3-ene-1,5,7-triyne 2. The solid-state structure of 2, containing a bent carbon chain between two ferrocenes, has been determined. The nonlinear optical properties of 2 were also investigated.

KW - Crystal structures

KW - Enynes

KW - Ferrocenes

KW - Optical nonlinearity

KW - Polyynes

UR - http://www.scopus.com/inward/record.url?scp=10944246147&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=10944246147&partnerID=8YFLogxK

U2 - 10.3184/0308234043431771

DO - 10.3184/0308234043431771

M3 - Article

SP - 714

EP - 715

JO - Journal of Chemical Research - Part S

JF - Journal of Chemical Research - Part S

SN - 0308-2342

IS - 10

ER -