Multi-purpose bonding performance of newly synthesized phosphonic acid monomers

Kunio Ikemura, Franklin Chi Meng Tay, Norihiro Nishiyama, David Henry Pashley, Takeshi Endo

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

Multi-purpose bonding performance of three kinds of newly synthesized phosphonic acid monomers was investigated. Methacryloxyalkyl or acryloxyalkyl phosphonoacetates of 6-MHPA, 6-AHPA, 10-MDPA were synthesized in 42.8-51.9% yields with a light yellow viscous liquid, and identified as new compounds by 1H NMR, IR, and elemental analysis. Conventional adhesive monomers, namely VBPA, 4-META, and 4-AETA, and CEBA-p-TSMo-t-BPMA initiator were also used. Seven experimental composite-type adhesive resins comprising these six kinds of adhesive monomers and None (control) with the initiator were prepared. Tensile bond strengths of adhesive resins to unetched ground enamel and dentin, ground porcelain, and sandblasted Ni-Cr alloy were measured at a crosshead speed of 1.0 mm/min. Results showed that except with VBPA, there were no significant differences among 6-MHPA, 6-AHPA, 10-MDPA, 4-AETA, and 4-META in bonding performance to the adherends (p<0.01). It was found that the new phosphonic acid monomers provided good multi-purpose adhesion to all adherends tested.

Original languageEnglish (US)
Pages (from-to)105-115
Number of pages11
JournalDental Materials Journal
Volume26
Issue number1
DOIs
StatePublished - Jan 1 2007

Fingerprint

Adhesives
Monomers
Acids
Resins
Phosphonoacetic Acid
Dental Porcelain
Porcelain
Enamels
Composite Resins
Tensile Strength
Bond strength (materials)
Dentin
Dental Enamel
Adhesion
Nuclear magnetic resonance
phosphonic acid
Composite materials
Liquids
Chemical analysis
4-methacryloxyethyltrimellitic acid anhydride

Keywords

  • Multi-purpose bonding performance
  • Phosphonic acid monomers
  • Polymerization initiator

ASJC Scopus subject areas

  • Ceramics and Composites
  • Dentistry(all)

Cite this

Multi-purpose bonding performance of newly synthesized phosphonic acid monomers. / Ikemura, Kunio; Tay, Franklin Chi Meng; Nishiyama, Norihiro; Pashley, David Henry; Endo, Takeshi.

In: Dental Materials Journal, Vol. 26, No. 1, 01.01.2007, p. 105-115.

Research output: Contribution to journalArticle

Ikemura, Kunio ; Tay, Franklin Chi Meng ; Nishiyama, Norihiro ; Pashley, David Henry ; Endo, Takeshi. / Multi-purpose bonding performance of newly synthesized phosphonic acid monomers. In: Dental Materials Journal. 2007 ; Vol. 26, No. 1. pp. 105-115.
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