Reaction of [μ-RE(μ-CO)Fe2(CO)6]- (E = S, Se) with N2CHCO2Me. Synthesis and characterisation of (μ-RE)[μ-η2-N=NCH(R′)CO2Me]Fe 2(CO)6 and (μ-PhSe)[μ-η1-N=NCH(Me)CO2Me]Fe 2(CO)6

Zhong Xia Wang; Shao Bin Miao; Ze Ying Zhang

doi:10.1016/S0022-328X(00)00246-1

Reaction of [μ-RE(μ-CO)Fe₂(CO)₆]^- (E = S, Se) with N₂CHCO₂Me. Synthesis and characterisation of (μ-RE)[μ-η²-N=NCH(R′)CO₂Me]Fe ₂(CO)₆ and (μ-PhSe)[μ-η¹-N=NCH(Me)CO₂Me]Fe ₂(CO)₆

Zhong Xia Wang, Shao Bin Miao, Ze Ying Zhang

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Reaction of [M][(μ-RE)(μ-CO)Fe₂(CO)₆] (E = S, Se; M = Et₃NH, Na) with N2CHCO2Me give the intermediate [M][(μ-RE)(μ-N₂CHCO₂Me)Fe₂(CO) ₆] (II). Action of II with counterion Et₃NH⁺ yields neutral complexes (μ-RE)(μ-η²-N=NCH₂CO₂Me)Fe ₂(CO)₆ (1, RE = Bu^tS; 2, RE = PhS; 3, RE = PhSe). Treatment of II (M=Na) with MeI affords (μ-RE)[μ-η²-N=NCH(Me)CO₂Me]Fe ₂(CO)₆ (4, RE = Bu^tS; 5, RE = PhS). In the case of RE = PhSe, the reaction of II with MeI gives two isomers, (μ-PhSe)[μ-η²-N=NCH(Me)CO₂Me]Fe ₂(CO)₆ (6) and (μ-PhSe)[μ-η¹-N=NCH(Me)CO₂Me]Fe ₂(CO)₆ (7). The structure of complex 7 has been determined by single-crystal X-ray diffraction technique.

Original language	English (US)
Pages (from-to)	214-218
Number of pages	5
Journal	Journal of Organometallic Chemistry
Volume	604
Issue number	2
DOIs	https://doi.org/10.1016/S0022-328X(00)00246-1
State	Published - Jun 16 2000
Externally published	Yes

Keywords

Complex
Diazenido ligand
Iron
Selenium
Structure
Sulfur
Synthesis

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S0022-328X(00)00246-1

Cite this

Reaction of [μ-RE(μ-CO)Fe₂(CO)₆]^- (E = S, Se) with N₂CHCO₂Me. Synthesis and characterisation of (μ-RE)[μ-η²-N=NCH(R′)CO₂Me]Fe ₂(CO)₆ and (μ-PhSe)[μ-η¹-N=NCH(Me)CO₂Me]Fe ₂(CO)₆. / Wang, Zhong Xia; Miao, Shao Bin; Zhang, Ze Ying.
In: Journal of Organometallic Chemistry, Vol. 604, No. 2, 16.06.2000, p. 214-218.

Research output: Contribution to journal › Article › peer-review

@article{096be5b6e3ab42878686b067183de5c0,

title = "Reaction of [μ-RE(μ-CO)Fe2(CO)6]- (E = S, Se) with N2CHCO2Me. Synthesis and characterisation of (μ-RE)[μ-η2-N=NCH(R′)CO2Me]Fe 2(CO)6 and (μ-PhSe)[μ-η1-N=NCH(Me)CO2Me]Fe 2(CO)6",

abstract = "Reaction of [M][(μ-RE)(μ-CO)Fe2(CO)6] (E = S, Se; M = Et3NH, Na) with N2CHCO2Me give the intermediate [M][(μ-RE)(μ-N2CHCO2Me)Fe2(CO) 6] (II). Action of II with counterion Et3NH+ yields neutral complexes (μ-RE)(μ-η2-N=NCH2CO2Me)Fe 2(CO)6 (1, RE = ButS; 2, RE = PhS; 3, RE = PhSe). Treatment of II (M=Na) with MeI affords (μ-RE)[μ-η2-N=NCH(Me)CO2Me]Fe 2(CO)6 (4, RE = ButS; 5, RE = PhS). In the case of RE = PhSe, the reaction of II with MeI gives two isomers, (μ-PhSe)[μ-η2-N=NCH(Me)CO2Me]Fe 2(CO)6 (6) and (μ-PhSe)[μ-η1-N=NCH(Me)CO2Me]Fe 2(CO)6 (7). The structure of complex 7 has been determined by single-crystal X-ray diffraction technique.",

keywords = "Complex, Diazenido ligand, Iron, Selenium, Structure, Sulfur, Synthesis",

author = "Wang, {Zhong Xia} and Miao, {Shao Bin} and Zhang, {Ze Ying}",

note = "Funding Information: We thank the Chinese Academy of Sciences and the Educational Ministry of China for financial support. ",

year = "2000",

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T1 - Reaction of [μ-RE(μ-CO)Fe2(CO)6]- (E = S, Se) with N2CHCO2Me. Synthesis and characterisation of (μ-RE)[μ-η2-N=NCH(R′)CO2Me]Fe 2(CO)6 and (μ-PhSe)[μ-η1-N=NCH(Me)CO2Me]Fe 2(CO)6

AU - Wang, Zhong Xia

AU - Miao, Shao Bin

AU - Zhang, Ze Ying

N1 - Funding Information: We thank the Chinese Academy of Sciences and the Educational Ministry of China for financial support.

PY - 2000/6/16

Y1 - 2000/6/16

N2 - Reaction of [M][(μ-RE)(μ-CO)Fe2(CO)6] (E = S, Se; M = Et3NH, Na) with N2CHCO2Me give the intermediate [M][(μ-RE)(μ-N2CHCO2Me)Fe2(CO) 6] (II). Action of II with counterion Et3NH+ yields neutral complexes (μ-RE)(μ-η2-N=NCH2CO2Me)Fe 2(CO)6 (1, RE = ButS; 2, RE = PhS; 3, RE = PhSe). Treatment of II (M=Na) with MeI affords (μ-RE)[μ-η2-N=NCH(Me)CO2Me]Fe 2(CO)6 (4, RE = ButS; 5, RE = PhS). In the case of RE = PhSe, the reaction of II with MeI gives two isomers, (μ-PhSe)[μ-η2-N=NCH(Me)CO2Me]Fe 2(CO)6 (6) and (μ-PhSe)[μ-η1-N=NCH(Me)CO2Me]Fe 2(CO)6 (7). The structure of complex 7 has been determined by single-crystal X-ray diffraction technique.

AB - Reaction of [M][(μ-RE)(μ-CO)Fe2(CO)6] (E = S, Se; M = Et3NH, Na) with N2CHCO2Me give the intermediate [M][(μ-RE)(μ-N2CHCO2Me)Fe2(CO) 6] (II). Action of II with counterion Et3NH+ yields neutral complexes (μ-RE)(μ-η2-N=NCH2CO2Me)Fe 2(CO)6 (1, RE = ButS; 2, RE = PhS; 3, RE = PhSe). Treatment of II (M=Na) with MeI affords (μ-RE)[μ-η2-N=NCH(Me)CO2Me]Fe 2(CO)6 (4, RE = ButS; 5, RE = PhS). In the case of RE = PhSe, the reaction of II with MeI gives two isomers, (μ-PhSe)[μ-η2-N=NCH(Me)CO2Me]Fe 2(CO)6 (6) and (μ-PhSe)[μ-η1-N=NCH(Me)CO2Me]Fe 2(CO)6 (7). The structure of complex 7 has been determined by single-crystal X-ray diffraction technique.

KW - Complex

KW - Diazenido ligand

KW - Iron

KW - Selenium

KW - Structure

KW - Sulfur

KW - Synthesis

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