Reaction of [Et3NH][(μ-RE)(μ-CO)Fe2(CO)6] (E=S, Se) with azides. Synthesis of (μ-RE)(μ-p-R1C6H4N3H)Fe 2(CO)6 and crystal structure of (μ-ButS)(μ-PhN3H)Fe2(CO)6

Zhong Xia Wang; Shao Bin Miao; Zhong Yuan Zhou; Xiang Ge Zhou

doi:10.1016/S0022-328X(00)00039-5

Reaction of [Et₃NH][(μ-RE)(μ-CO)Fe₂(CO)₆] (E=S, Se) with azides. Synthesis of (μ-RE)(μ-p-R¹C₆H₄N₃H)Fe ₂(CO)₆ and crystal structure of (μ-Bu^tS)(μ-PhN₃H)Fe₂(CO)₆

Zhong Xia Wang, Shao Bin Miao, Zhong Yuan Zhou, Xiang Ge Zhou

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The reaction of [Et₃NH][(μ-RE)(μ-CO)Fe₂(CO)₆] (E=S, Se) (1) with aryl azides gives bridging triazenido complexes (μ-RE)(μ-p-R¹C₆H₄N₃H)Fe ₂(CO)₆ (2-8) (2, RE=Bu^tS, R¹=H; 3, RE=PhS, R¹=H; 4, RE=Bu^tS, R¹=Cl; 5, RE=Bu^tS, R¹=MeO; 6, RE=PhS, R¹=MeO; 7, RE=PhSe, R¹=H; 8, RE=PhSe, R¹=Cl). These complexes were characterized by elemental analyses and ¹H-NMR and IR spectroscopy. The structure of complex 2, established by single-crystal X-ray diffraction analysis, shows that the triazenido ligand binds to two iron centers in a bridging bidentate fashion.

Original language	English (US)
Pages (from-to)	87-92
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	601
Issue number	1
DOIs	https://doi.org/10.1016/S0022-328X(00)00039-5
State	Published - Apr 20 2000
Externally published	Yes

Keywords

Complex
Iron
Selenium
Structure
Sulfur
Triazenido ligand

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S0022-328X(00)00039-5

Cite this

Reaction of [Et₃NH][(μ-RE)(μ-CO)Fe₂(CO)₆] (E=S, Se) with azides. Synthesis of (μ-RE)(μ-p-R¹C₆H₄N₃H)Fe ₂(CO)₆ and crystal structure of (μ-Bu^tS)(μ-PhN₃H)Fe₂(CO)₆. / Wang, Zhong Xia; Miao, Shao Bin; Zhou, Zhong Yuan et al.
In: Journal of Organometallic Chemistry, Vol. 601, No. 1, 20.04.2000, p. 87-92.

Research output: Contribution to journal › Article › peer-review

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title = "Reaction of [Et3NH][(μ-RE)(μ-CO)Fe2(CO)6] (E=S, Se) with azides. Synthesis of (μ-RE)(μ-p-R1C6H4N3H)Fe 2(CO)6 and crystal structure of (μ-ButS)(μ-PhN3H)Fe2(CO)6",

abstract = "The reaction of [Et3NH][(μ-RE)(μ-CO)Fe2(CO)6] (E=S, Se) (1) with aryl azides gives bridging triazenido complexes (μ-RE)(μ-p-R1C6H4N3H)Fe 2(CO)6 (2-8) (2, RE=ButS, R1=H; 3, RE=PhS, R1=H; 4, RE=ButS, R1=Cl; 5, RE=ButS, R1=MeO; 6, RE=PhS, R1=MeO; 7, RE=PhSe, R1=H; 8, RE=PhSe, R1=Cl). These complexes were characterized by elemental analyses and 1H-NMR and IR spectroscopy. The structure of complex 2, established by single-crystal X-ray diffraction analysis, shows that the triazenido ligand binds to two iron centers in a bridging bidentate fashion.",

keywords = "Complex, Iron, Selenium, Structure, Sulfur, Triazenido ligand",

author = "Wang, {Zhong Xia} and Miao, {Shao Bin} and Zhou, {Zhong Yuan} and Zhou, {Xiang Ge}",

note = "Funding Information: We thank the Chinese Academy of Sciences and the Educational Ministry of China for financial support.",

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AU - Miao, Shao Bin

AU - Zhou, Zhong Yuan

AU - Zhou, Xiang Ge

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PY - 2000/4/20

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N2 - The reaction of [Et3NH][(μ-RE)(μ-CO)Fe2(CO)6] (E=S, Se) (1) with aryl azides gives bridging triazenido complexes (μ-RE)(μ-p-R1C6H4N3H)Fe 2(CO)6 (2-8) (2, RE=ButS, R1=H; 3, RE=PhS, R1=H; 4, RE=ButS, R1=Cl; 5, RE=ButS, R1=MeO; 6, RE=PhS, R1=MeO; 7, RE=PhSe, R1=H; 8, RE=PhSe, R1=Cl). These complexes were characterized by elemental analyses and 1H-NMR and IR spectroscopy. The structure of complex 2, established by single-crystal X-ray diffraction analysis, shows that the triazenido ligand binds to two iron centers in a bridging bidentate fashion.

AB - The reaction of [Et3NH][(μ-RE)(μ-CO)Fe2(CO)6] (E=S, Se) (1) with aryl azides gives bridging triazenido complexes (μ-RE)(μ-p-R1C6H4N3H)Fe 2(CO)6 (2-8) (2, RE=ButS, R1=H; 3, RE=PhS, R1=H; 4, RE=ButS, R1=Cl; 5, RE=ButS, R1=MeO; 6, RE=PhS, R1=MeO; 7, RE=PhSe, R1=H; 8, RE=PhSe, R1=Cl). These complexes were characterized by elemental analyses and 1H-NMR and IR spectroscopy. The structure of complex 2, established by single-crystal X-ray diffraction analysis, shows that the triazenido ligand binds to two iron centers in a bridging bidentate fashion.

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