Structural conformers of symmetry substituted resorcin[4]arenes

Shaobin Miao, Richard D. Adams, Dian Shun Guo, Qian Feng Zhang

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

Methylresorcin[4]arenes in the C2h and C4v symmetrical chair and crown conformers, and resorcin[4]arene in the C 2v symmetrical boat conformation have been synthesized from the typical one-pot acid-catalyzed reaction and structurally characterized. Solvation of organic molecules in the crystalline state of the chair and boat isomers shows inter-resorcin[4]arene interactions held together by intermolecular hydrogen bonds involving solvate molecules. The intramolecular hydrogen bonds naturally form in the crown isomer of the substituted resorcin[4]arenes.

Original languageEnglish (US)
Pages (from-to)119-128
Number of pages10
JournalJournal of Molecular Structure
Volume659
Issue number1-3
DOIs
StatePublished - Oct 29 2003
Externally publishedYes

Fingerprint

Boats
Isomers
Hydrogen bonds
Molecules
Solvation
Conformations
Crystalline materials
Acids
resorcinol
resorcinarene

Keywords

  • Hydrogen-bonding
  • Resorcin[4]arene
  • Self-assembly
  • Structure
  • Supramolecular chemistry

ASJC Scopus subject areas

  • Analytical Chemistry
  • Spectroscopy
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

Structural conformers of symmetry substituted resorcin[4]arenes. / Miao, Shaobin; Adams, Richard D.; Guo, Dian Shun; Zhang, Qian Feng.

In: Journal of Molecular Structure, Vol. 659, No. 1-3, 29.10.2003, p. 119-128.

Research output: Contribution to journalArticle

Miao, Shaobin ; Adams, Richard D. ; Guo, Dian Shun ; Zhang, Qian Feng. / Structural conformers of symmetry substituted resorcin[4]arenes. In: Journal of Molecular Structure. 2003 ; Vol. 659, No. 1-3. pp. 119-128.
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