Abstract
High resolution, two-dimensional 1H-n.m.r. spectroscopy has been used to confirm a proposed primary structure of a glycolipid having an octasaccharide head-group. Pure absorption and relay experiments were found to be particularly useful in establishing connectivities in poorly resolved regions of the spectrum. The spectral assignments, which indicate novel linkages including an internal fucopyranosyl residue as well as terminal xylosyl and 4-O-methylglucopyranosyluronic acid groups, add to a growing data base for structural characterization through n.m.r. spectroscopy.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 45-56 |
| Number of pages | 12 |
| Journal | Carbohydrate Research |
| Volume | 155 |
| Issue number | C |
| DOIs | |
| State | Published - Nov 1 1986 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Analytical Chemistry
- Biochemistry
- Organic Chemistry
Cite this
1H-2D-nuclear magnetic resonance applied to the primary structure determination of a novel octasaccharide glycolipid isolated from the spermatozoa of bivalves. / Neel Scarsdale, J.; Prestegard, James H.; Ando, Susumu; Hori, Taro; Yu, Robert K.
In: Carbohydrate Research, Vol. 155, No. C, 01.11.1986, p. 45-56.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - 1H-2D-nuclear magnetic resonance applied to the primary structure determination of a novel octasaccharide glycolipid isolated from the spermatozoa of bivalves
AU - Neel Scarsdale, J.
AU - Prestegard, James H.
AU - Ando, Susumu
AU - Hori, Taro
AU - Yu, Robert K
PY - 1986/11/1
Y1 - 1986/11/1
N2 - High resolution, two-dimensional 1H-n.m.r. spectroscopy has been used to confirm a proposed primary structure of a glycolipid having an octasaccharide head-group. Pure absorption and relay experiments were found to be particularly useful in establishing connectivities in poorly resolved regions of the spectrum. The spectral assignments, which indicate novel linkages including an internal fucopyranosyl residue as well as terminal xylosyl and 4-O-methylglucopyranosyluronic acid groups, add to a growing data base for structural characterization through n.m.r. spectroscopy.
AB - High resolution, two-dimensional 1H-n.m.r. spectroscopy has been used to confirm a proposed primary structure of a glycolipid having an octasaccharide head-group. Pure absorption and relay experiments were found to be particularly useful in establishing connectivities in poorly resolved regions of the spectrum. The spectral assignments, which indicate novel linkages including an internal fucopyranosyl residue as well as terminal xylosyl and 4-O-methylglucopyranosyluronic acid groups, add to a growing data base for structural characterization through n.m.r. spectroscopy.
UR - http://www.scopus.com/inward/record.url?scp=0022819464&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0022819464&partnerID=8YFLogxK
U2 - 10.1016/S0008-6215(00)90132-0
DO - 10.1016/S0008-6215(00)90132-0
M3 - Article
C2 - 3791301
AN - SCOPUS:0022819464
VL - 155
SP - 45
EP - 56
JO - Carbohydrate Research
JF - Carbohydrate Research
SN - 0008-6215
IS - C
ER -