Synthesis and characterization of group VIB metal carbonyl heteroacene complexes

Xianwei Cui, John J. Hoff, Jason D. Ji, Thomas Albers, Jingzhe Zhao, Weimin He, Lei Zhu, Shaobin Miao

Research output: Contribution to journalArticle

4 Scopus citations

Abstract

Group VIB metal carbonyl heteroacene complexes were synthesized and characterized. Single crystal X-ray diffraction confirms that all metal carbonyl complexes bond to the ligand through the phenanthroline unit. Their absorption spectra are red-shifted compared to that of the ligand and their cyclic voltammetry revealed that their reduction occurred at less reducing potentials than the corresponding reduction in ligand.

Original languageEnglish (US)
Pages (from-to)145-150
Number of pages6
JournalInorganica Chimica Acta
Volume442
DOIs
StatePublished - Mar 1 2016

Keywords

  • Crystal structures
  • Electrochemical properties
  • N-fused acene
  • Synthesis
  • Transition metal

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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