Synthesis and characterization of group VIB metal carbonyl heteroacene complexes

Xianwei Cui, John J. Hoff, Jason D. Ji, Thomas Albers, Jingzhe Zhao, Weimin He, Lei Zhu, Shaobin Miao

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Group VIB metal carbonyl heteroacene complexes were synthesized and characterized. Single crystal X-ray diffraction confirms that all metal carbonyl complexes bond to the ligand through the phenanthroline unit. Their absorption spectra are red-shifted compared to that of the ligand and their cyclic voltammetry revealed that their reduction occurred at less reducing potentials than the corresponding reduction in ligand.

Original languageEnglish (US)
Pages (from-to)145-150
Number of pages6
JournalInorganica Chimica Acta
Volume442
DOIs
StatePublished - Mar 1 2016

Fingerprint

Metals
Ligands
ligands
synthesis
metals
Phenanthrolines
Cyclic voltammetry
Absorption spectra
Single crystals
absorption spectra
X ray diffraction
single crystals
diffraction
x rays

Keywords

  • Crystal structures
  • Electrochemical properties
  • N-fused acene
  • Synthesis
  • Transition metal

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Synthesis and characterization of group VIB metal carbonyl heteroacene complexes. / Cui, Xianwei; Hoff, John J.; Ji, Jason D.; Albers, Thomas; Zhao, Jingzhe; He, Weimin; Zhu, Lei; Miao, Shaobin.

In: Inorganica Chimica Acta, Vol. 442, 01.03.2016, p. 145-150.

Research output: Contribution to journalArticle

Cui, Xianwei ; Hoff, John J. ; Ji, Jason D. ; Albers, Thomas ; Zhao, Jingzhe ; He, Weimin ; Zhu, Lei ; Miao, Shaobin. / Synthesis and characterization of group VIB metal carbonyl heteroacene complexes. In: Inorganica Chimica Acta. 2016 ; Vol. 442. pp. 145-150.
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AU - Miao, Shaobin

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