Abstract
Group VIB metal carbonyl heteroacene complexes were synthesized and characterized. Single crystal X-ray diffraction confirms that all metal carbonyl complexes bond to the ligand through the phenanthroline unit. Their absorption spectra are red-shifted compared to that of the ligand and their cyclic voltammetry revealed that their reduction occurred at less reducing potentials than the corresponding reduction in ligand.
Original language | English (US) |
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Pages (from-to) | 145-150 |
Number of pages | 6 |
Journal | Inorganica Chimica Acta |
Volume | 442 |
DOIs | |
State | Published - Mar 1 2016 |
Keywords
- Crystal structures
- Electrochemical properties
- N-fused acene
- Synthesis
- Transition metal
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry