Abstract
Two new aza-acenequinone derivatives 4 and 5 were prepared by cyclocondensation of diamines 2 and 3 with bis(triisopropylsilyl)-dialkynyl-l,2-dione 1. Further reactions of compounds 4 and 5 with malononitrile using the Lehnert reagent afforded corresponding tetracyanoquinodimethane (TCNQ) derivatives 6 and 7. Compounds 4, 6 and 7 were characterized by single crystal X-ray diffraction techniques. Compounds 6 and 7 were studied electrochemically and photochemically. Density functional theory (DFT) calculations on compounds 6 and 7 indicate that both compounds have the potential to be candidates for organic semiconductor materials.
Original language | English (US) |
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Pages (from-to) | 249-254 |
Number of pages | 6 |
Journal | Heterocyclic Communications |
Volume | 24 |
Issue number | 5 |
DOIs | |
State | Published - Oct 25 2018 |
Externally published | Yes |
Keywords
- Lehnert reagent
- TCNQ derivatives
- organic semiconductor
- single crystal X-ray structure
ASJC Scopus subject areas
- Organic Chemistry