Synthesis of large pyrene-fused azaacenes

Jason D. Ji; Lei Zhu; Christopher L Klug; Mark D. Smith; Shaobin Miao

doi:10.1055/s-0034-1379965

Synthesis of large pyrene-fused azaacenes

Jason D. Ji, Lei Zhu, Christopher L Klug, Mark D. Smith, Shaobin Miao

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The facile synthesis of pyrene-fused tetraazaheptacene and tetraazaoctacene is reported. The new compounds are fully soluble in common organic solvents. The absorption spectra of both compounds reveal that they have low energy gaps. The structure of tetraazaoctacene was confirmed by single crystal X-ray diffraction analysis.

Original language	English (US)
Article number	ss-2014-m0692-op
Journal	Synthesis (Germany)
Volume	46
Issue number	1
DOIs	https://doi.org/10.1055/s-0034-1379965
State	Published - Jan 16 2015

Keywords

azaacenes
crystal structures
electronic materials
pyrene
solubility

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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10.1055/s-0034-1379965

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abstract = "The facile synthesis of pyrene-fused tetraazaheptacene and tetraazaoctacene is reported. The new compounds are fully soluble in common organic solvents. The absorption spectra of both compounds reveal that they have low energy gaps. The structure of tetraazaoctacene was confirmed by single crystal X-ray diffraction analysis.",

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author = "Ji, {Jason D.} and Lei Zhu and Klug, {Christopher L} and Smith, {Mark D.} and Shaobin Miao",

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AU - Ji, Jason D.

AU - Zhu, Lei

AU - Klug, Christopher L

AU - Smith, Mark D.

AU - Miao, Shaobin

N1 - Publisher Copyright: © Georg Thieme Verlag Stuttgart, New York.

PY - 2015/1/16

Y1 - 2015/1/16

N2 - The facile synthesis of pyrene-fused tetraazaheptacene and tetraazaoctacene is reported. The new compounds are fully soluble in common organic solvents. The absorption spectra of both compounds reveal that they have low energy gaps. The structure of tetraazaoctacene was confirmed by single crystal X-ray diffraction analysis.

AB - The facile synthesis of pyrene-fused tetraazaheptacene and tetraazaoctacene is reported. The new compounds are fully soluble in common organic solvents. The absorption spectra of both compounds reveal that they have low energy gaps. The structure of tetraazaoctacene was confirmed by single crystal X-ray diffraction analysis.

KW - azaacenes

KW - crystal structures

KW - electronic materials

KW - pyrene

KW - solubility

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ER -

Synthesis of large pyrene-fused azaacenes

Abstract

Keywords

ASJC Scopus subject areas

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