Toward effective and tunable interphases in graphene oxide/epoxy composites by grafting different chain lengths of polyetheramine onto graphene oxide

Li Zhi Guan, Yan Jun Wan, Li Xiu Gong, Dong Yan, Long Cheng Tang, Lian Bin Wu, Jian Xiong Jiang, Guo Qiao Lai

Research output: Contribution to journalArticle

124 Citations (Scopus)

Abstract

Interface design plays a crucial role in developing superior mechanical performance of graphene/polymer nanocomposites. Herein, we report a facile approach to the fabrication of advanced polymeric nanocomposites of epoxy by the incorporation of polyetheramine-functionalized graphene oxide (PEA-f-GO). Two types of PEA molecules with different molecular lengths were used to synthesize the PEA-f-GO sheets. The chemical bonds formed between the amine functional groups on the GO surface and the epoxy resin during curing provided strong sheet/matrix interfacial adhesion. The addition of PEA-f-GO was found to produce significant enhancements in the mechanical properties of epoxy, including elastic modulus, tensile strength, elongation at break and toughness. In particular, the PEA-f-GO sheets containing shorter PEA molecules produced higher improvement in strength but smaller increases in both ductility and toughness than those containing longer PEA molecules. For example, at 0.50 wt% filler loading, two nanocomposites showed increases of 63% and 51% in tensile strength and 90% and 119% in toughness as compared to the unfilled epoxy. Our results suggest that the interphases between the GO and the polymer matrix can be tuned by varying the molecular lengths of grafted modifiers, thereby providing a new route for the rational designing and development of the GO-based composite materials.

Original languageEnglish (US)
Pages (from-to)15058-15069
Number of pages12
JournalJournal of Materials Chemistry A
Volume2
Issue number36
DOIs
StatePublished - Sep 28 2014

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Graphite
Chain length
Oxides
Graphene
Composite materials
Toughness
Nanocomposites
Molecules
Tensile strength
Epoxy Resins
Chemical bonds
Polymer matrix
Epoxy resins
Functional groups
Amines
Ductility
Curing
Fillers
Elongation
Polymers

ASJC Scopus subject areas

  • Chemistry(all)
  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)

Cite this

Toward effective and tunable interphases in graphene oxide/epoxy composites by grafting different chain lengths of polyetheramine onto graphene oxide. / Guan, Li Zhi; Wan, Yan Jun; Gong, Li Xiu; Yan, Dong; Tang, Long Cheng; Wu, Lian Bin; Jiang, Jian Xiong; Lai, Guo Qiao.

In: Journal of Materials Chemistry A, Vol. 2, No. 36, 28.09.2014, p. 15058-15069.

Research output: Contribution to journalArticle

Guan, Li Zhi ; Wan, Yan Jun ; Gong, Li Xiu ; Yan, Dong ; Tang, Long Cheng ; Wu, Lian Bin ; Jiang, Jian Xiong ; Lai, Guo Qiao. / Toward effective and tunable interphases in graphene oxide/epoxy composites by grafting different chain lengths of polyetheramine onto graphene oxide. In: Journal of Materials Chemistry A. 2014 ; Vol. 2, No. 36. pp. 15058-15069.
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