Trinuclear metal clusters with three different metal atoms from the insertion of CpCo and Cp*Rh groups into the S-S bonds of [CpFeMn(CO) 5(μ-S2)]2

Richard D. Adams; Erin Boswell; Shaobin Miao; Sanghamitra Sanyal

doi:10.1007/s10876-005-4397-8

Trinuclear metal clusters with three different metal atoms from the insertion of CpCo and Cp*Rh groups into the S-S bonds of [CpFeMn(CO) ₅(μ-S₂)]₂

Richard D. Adams, Erin Boswell, Shaobin Miao, Sanghamitra Sanyal

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Two cobalt containing products CpCoMn₂(CO) ₆(μ₃-S)₂, 2 and Cp₂FeCoMn(CO) ₃(μ₃-S)₂, 3 were obtained from the reaction of [CpFeMn(CO)₅(μ-S₂)]₂, 1 with CpCo(CO)₂ at room temperature. The two rhodium containing products: Cp*RhMn₂(CO)₆(μ₃-S)₂, 4 (11% yield) and CpFeCp*RhMn(CO)₃(μ₃-S) ₂, 5 (9% yield), were obtained from the reaction of 1 with Cp*Rh(CO)₂. Compounds 3 and 5 were characterized structurally by single crystal X-ray diffraction methods. Compounds 3 and 5 both contain triangular clusters of three different types of metal atoms and have triply bridging sulfido ligands on each side of the cluster. A mechanism for their formation from 1 is proposed.

Original language	English (US)
Pages (from-to)	117-126
Number of pages	10
Journal	Journal of Cluster Science
Volume	16
Issue number	2
DOIs	https://doi.org/10.1007/s10876-005-4397-8
State	Published - Jun 2005
Externally published	Yes

Keywords

Disulfido ligand
Iron
Manganese
Mixed metal cluster
Rhodium
cobalt

ASJC Scopus subject areas

Biochemistry
General Chemistry
General Materials Science
Condensed Matter Physics

Access to Document

10.1007/s10876-005-4397-8

Cite this

@article{3505fbe5b37d497690c1cf08790e9ad4,

title = "Trinuclear metal clusters with three different metal atoms from the insertion of CpCo and Cp*Rh groups into the S-S bonds of [CpFeMn(CO) 5(μ-S2)]2",

abstract = "Two cobalt containing products CpCoMn2(CO) 6(μ3-S)2, 2 and Cp2FeCoMn(CO) 3(μ3-S)2, 3 were obtained from the reaction of [CpFeMn(CO)5(μ-S2)]2, 1 with CpCo(CO)2 at room temperature. The two rhodium containing products: Cp*RhMn2(CO)6(μ3-S)2, 4 (11% yield) and CpFeCp*RhMn(CO)3(μ3-S) 2, 5 (9% yield), were obtained from the reaction of 1 with Cp*Rh(CO)2. Compounds 3 and 5 were characterized structurally by single crystal X-ray diffraction methods. Compounds 3 and 5 both contain triangular clusters of three different types of metal atoms and have triply bridging sulfido ligands on each side of the cluster. A mechanism for their formation from 1 is proposed.",

keywords = "Disulfido ligand, Iron, Manganese, Mixed metal cluster, Rhodium, cobalt",

author = "Adams, {Richard D.} and Erin Boswell and Shaobin Miao and Sanghamitra Sanyal",

note = "Funding Information: This research was supported by a grant from the National Science Foundation, Grant No. CHE-0354892 and the USC NanoCenter.",

year = "2005",

month = jun,

doi = "10.1007/s10876-005-4397-8",

language = "English (US)",

volume = "16",

pages = "117--126",

journal = "Journal of Cluster Science",

issn = "1040-7278",

publisher = "Springer New York",

number = "2",

}

TY - JOUR

T1 - Trinuclear metal clusters with three different metal atoms from the insertion of CpCo and Cp*Rh groups into the S-S bonds of [CpFeMn(CO) 5(μ-S2)]2

AU - Adams, Richard D.

AU - Boswell, Erin

AU - Miao, Shaobin

AU - Sanyal, Sanghamitra

N1 - Funding Information: This research was supported by a grant from the National Science Foundation, Grant No. CHE-0354892 and the USC NanoCenter.

PY - 2005/6

Y1 - 2005/6

N2 - Two cobalt containing products CpCoMn2(CO) 6(μ3-S)2, 2 and Cp2FeCoMn(CO) 3(μ3-S)2, 3 were obtained from the reaction of [CpFeMn(CO)5(μ-S2)]2, 1 with CpCo(CO)2 at room temperature. The two rhodium containing products: Cp*RhMn2(CO)6(μ3-S)2, 4 (11% yield) and CpFeCp*RhMn(CO)3(μ3-S) 2, 5 (9% yield), were obtained from the reaction of 1 with Cp*Rh(CO)2. Compounds 3 and 5 were characterized structurally by single crystal X-ray diffraction methods. Compounds 3 and 5 both contain triangular clusters of three different types of metal atoms and have triply bridging sulfido ligands on each side of the cluster. A mechanism for their formation from 1 is proposed.

AB - Two cobalt containing products CpCoMn2(CO) 6(μ3-S)2, 2 and Cp2FeCoMn(CO) 3(μ3-S)2, 3 were obtained from the reaction of [CpFeMn(CO)5(μ-S2)]2, 1 with CpCo(CO)2 at room temperature. The two rhodium containing products: Cp*RhMn2(CO)6(μ3-S)2, 4 (11% yield) and CpFeCp*RhMn(CO)3(μ3-S) 2, 5 (9% yield), were obtained from the reaction of 1 with Cp*Rh(CO)2. Compounds 3 and 5 were characterized structurally by single crystal X-ray diffraction methods. Compounds 3 and 5 both contain triangular clusters of three different types of metal atoms and have triply bridging sulfido ligands on each side of the cluster. A mechanism for their formation from 1 is proposed.

KW - Disulfido ligand

KW - Iron

KW - Manganese

KW - Mixed metal cluster

KW - Rhodium

KW - cobalt

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